Green Building Materials & Embodied Carbon Metrics: Pozzolanic Hydration Kinetics, Life Cycle Assessment (LCA), and Low-Carbon Cementitious Binders
Green building materials and carbon accounting frameworks are central to reducing the environmental footprint of modern civil infrastructure. Portland cement production alone accounts for approximately 8% of global anthropogenic carbon dioxide emissions, driven by limestone calcination and high-temperature clinker kiln operation. Lowering embodied carbon requires integrating industrial byproducts (such as fly ash, ground granulated blast-furnace slag [GGBS], and calcined clay) to formulate low-carbon ternary and quaternary blended cements. In supplementary cementitious materials (SCMs), silica ($SiO_2$) reacts with calcium hydroxide ($Ca(OH)_2$, Portlandite) liberated during primary alite/belite hydration to produce secondary strength-giving Calcium-Silicate-Hydrate ($C-S-H$) gel. The Pozzolanic Hydration Kinetic Model is expressed as: $$3 Ca(OH)_2 + 2 SiO_2 + n H_2O \rightarrow 3CaO \cdot 2SiO_2 \cdot (n+3)H_2O \quad (C-S-H \text{ gel})$$ The degree of hydration ($\alpha(t)$) ...