<p style="text-align: justify;">Advanced Oxidation Processes (AOPs) represent a class of chemical treatment procedures designed to remove recalcitrant organic contaminants, pharmaceuticals, endocrine-disrupting chemicals (EDCs), and persistent organic pollutants (POPs) from industrial and municipal water streams. AOPs rely on the in-situ generation of highly reactive, non-selective hydroxyl radicals ($\text{OH}^\bullet$, standard reduction potential $E^0 = 2.80\text{ V}$) to initiate rapid electrophilic attack and unselective mineralization of complex organic matrices into $\text{CO}_2$, $\text{H}_2\text{O}$, and inorganic salts.</p> <p style="text-align: justify;">The reaction rate of hydroxyl radical destruction with target organic pollutants ($R$) follows non-selective second-order reaction kinetics, limited primarily by mass transport and scavenging side-reactions:</p> <div class="has-jax"> $$-\frac{d[R]}{dt} = k_{\text{O...
Geotechnical Earthquake Engineering & Soil Liquefaction: Cyclic Stress Ratio, Pore Pressure Generation, and Liquefaction Mitigation Kinetics
Geotechnical earthquake engineering and soil liquefaction mechanics evaluate the behavior of soil deposits under dynamic seismic loading. Liquefaction primarily occurs in saturated, loose, cohesionless granular soils (such as clean sands and silty sands) subjected to cyclic ground motions. Under rapid cyclic shearing, the soil matrix tends to densify, transferring effective intergranular stress onto the pore fluid, causing a steep buildup of excess pore water pressure and a temporary total loss of shear strength. The seismic demand imposed on a soil layer at depth $z$ is quantified by the Cyclic Stress Ratio (CSR) based on the simplified procedure by Seed and Idriss: $$\text{CSR} = \frac{\tau_{\text{cyc}}}{\sigma'_{v0}} = 0.65 \cdot \left( \frac{a_{\text{max}}}{g} \right) \cdot \left( \frac{\sigma_{v0}}{\sigma'_{v0}} \right) \cdot r_d$$ Where $a_{\text{max}}$ is peak horizontal ground acceleration, $g$ is gravitational acceleration, $\sigma_{v0}$ is total vertical overb...